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Archive International Polymer Processing - Issue 2012/03 Back to overview
Bi-axially Oriented Blown Film Technology
Searching for Suitable Polymers and Processing Conditions
A set of commercial polyethylenes (three LDPE and three LLDPE) was rheological characterized and processed in a laboratory double bubble extrusion line with the purpose of investigating: i) whether their relative processability could be predicted in the laboratory and ii) the effect of operating and machine variables on processability. Oscillatory shear and extensional measurements were able to differentiate the various materials, who also behaved quite differently upon processing. Those with a stronger shear thinning behaviour, higher elasticity and higher melt strength were the most suited to the process. Bubble stability and thickness uniformity were assumed as the main requirements for processability. The former was estimated by monitoring the time required to stabilize the bubble and examining any variation/oscillation in size/shape. Bubble stability depends on the interaction between various parameters, the most relevant being those related with the film cooling stage, namely the axial position of the air rings, the air flow rate and air velocity. The study was preceded by an assessment of the performance of the re-heating oven and die/calibration/centring, as these parameters could also narrow the practical operating window.

From O. S. Carneiro 1 | J. A. Covas 1 | C. Domingues 1
1IPC/I3N – Institute for Polymers and Composites, Department of Polymer Engineering, University of Minho, Guimarães, Portugal
(Received 14.07.2011; accepted 08.12.2011)
Appeared in International Polymer Processing 2012/03, Page 348-357
DOI: 10.3139/217.2538
Direct link: http://www.polymer-process.com/IPP2538
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References
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1 Bobovitch, A. L., et al., “Orientation, Structure and Properties of Double-Bubble Oriented LLDPE Films”, J. Plastic Film and Sheeting, 22, 133–143 (2006a)., DOI: 10.1177/8756087906064891
2 Bobovitch, A. L., et al., “Mechanical Properties, Stress-relaxation and Orientation of Double Bubble Biaxially Oriented Polyethylene Films”, J. Appl. Polym. Sci., 100, 3545–3553 (2006b)., DOI: 10.1002/app.22727
3 Carneiro, O. S., et al., Portuguese Patent 103380 (2007).
4 Carneiro, O. S., et al., “Small-scale Production of Co-extruded Biaxially Oriented Blown Film”, Polym. Test., 27, 527–537 (2008)., DOI: 10.1016/j.polymertesting.2008.02.010
5 Di Maio, L., et al., “Biaxial Orientation of Polyamide Films: Processability and Properties”, Macromol. Symp., 180, 1–8 (2002)., DOI: 10.1002/1521-3900(200203)180:1<1::AID-MASY1>3.0.CO;2-X
6 Fang, Y. L., et al., “Rheological Effects of Polyethylenes in Film Blowing” Polym. Eng. Sci., 43, 1391–1406 (2003)., DOI: 10.1002/pen.10118
7 Field, G. J., et al., “Melt Strength and Film Bubble Instability of LLDPE/LDPE Blends”, Polym. Intern., 48, 461–466 (1999)., DOI: 10.1002/(SICI)1097- 0126(199906)48:6<461::AID-PI169>3.0.CO;2-7
8 Ghaneh-Fard, et al., “Study of Instabilities in Film Blowing”, AICHE J., 42, 1388–1396 (1996)., DOI: 10.1002/aic.690420519
9 Ghaneh-Fard, A., et al., “Study of Kinematics and Dynamics of Film Blowing of Different Polyethylenes”, Polym. Eng. Sci., 37, 1148 – 1163 (1997)., DOI: 10.1002/pen.11759
10 Ghijsels, A., et al., “Melt Strength Behavior of PE and its Relation to Bubble Stability in Film Blowing”, Int. Polym. Proc., 5, 284–286 (1990).
11 Ghijsels, A., et al., “Melt Strength Behavior of Polyethylene Blends”, Int. Polym. Proc., 7, 44–50 (1992).
12 Johnson, M. B., Wilkes, G. L., “Optical Properties of Blown and Cast Polyethylene Films: Surface versus Bulk Structural Considerations” J. Appl. Polym. Sci., 77, 2845–2864 (2000)., DOI: 10.1002/1097-4628(20000923)77:13<2845::AID-APP6>3.0.CO;2-7
13 Kanai, T., White, J. L. “Kinematics, Dynamics and Stability of Tubular Film Extrusion of Various Polyethylenes”, Polym. Eng. Sci., 24, 1185–1201 (1984)., DOI: 10.1002/pen.760241508
14 Kang, H. J., et al, “Single and Double Bubble Tubular Film Extrusion of Polyethylene Terephtalate”, Int. Polym. Proc., 5, 62–73 (1990).
15 La Mantia, F. P., Acierno, D., “Influence of the Molecular Structure on the Melt Strength and Extensibility of Polyethylenes” Polym. Eng. Sci., 25, 279–283 (1985)., DOI: 10.1002/pen.760250505
16 Lamontagne, N. D., “Flexible Packaging Offers Convenience and Cost Savings”, Plastics Engineering, 67, 1–11 (2011).
17 Larson, R. G.: Constitutive Equations for Polymer Melts and Solutions, Butterworth-Heinemann, Stoneham (1988).
18 Leal, V., et al., “New Results on the Correlation Molecular Architecture Melt Elasticity Blowing Process Film Properties for Conventional and Metallocene-catalyzed Polyethylenes”, Macromol. Mater. Eng., 291, 670–676 (2006)., DOI: 10.1002/mame.200600072
19 Majumder, K. K., et al., “Molecular, Rheological and Crystalline Properties of Low-density Polyethylene in Blown Film Extrusion”, Polym. Eng. Sci., 47, 1983–1991 (2007)., DOI: 10.1002/pen.20825
20 Micic, P., et al., “Melt Strength and Elastic Behavior of LLDPE/LDPE Blends”, Int. Polym. Proc., 11, 14–20 (1996).
21 Micic, P., Bhattacharya, S. N., “Rheology of LLDPE, LDPE and LLDPE/LDPE Blends and Its Relevance to the Film Blowing Process”, Polym. Int., 49, 1580–1589 (2000)., DOI: 10.1002/1097-0126(200012)49:12<1580::AID-PI547>3.0.CO;2-Q
22 Minoshima, W., White, J. L., “Instability Phenomena in Tubular Film and Melt spinning of Rheologically Characterized High Density, Low Density and Linear Low Density Polyethylenes”, J. Non-Newtonian Fluid Mech., 19, 275–302 (1986)., DOI: 10.1016/0377-0257(86)80053-2
23 Muke, S., et al., “Extensional Rheology of Polypropylene Melts from the Rheotens Test”, J. Non-Newtonian Fluid Mech., 101, 77–93 (2001)., DOI: 10.1016/S0377-0257(01)00142-2
24 Munstedt, H., et al., “Influence of Molecular Structure on Rheological Properties of Polyethylenes”, Rheol. Acta, 37, 21–29 (1998)., DOI: 10.1007/s003970050087
25 Rhee, S., White, J. L., “PA612 Double Bubble Tubular Film Process – Processability and Structure Development”, Int. Polym. Proc., 16, 272–284 (2001).
26 Song, K., White, J. L., “Single and Double Bubble Tubular Film Extrusion of Polybutylene Terephthalate”, Int. Polym. Proc., 15, 157–165 (2000).
27 Takashige, M., et al., “Scale-up Rule for Double Bubble Tubular Process of PA6 Film”, Int. Polym. Proc., 19, 368–375 (2003).
28 Takashige, M., et al., “Thickness Uniformity of Double Bubble Tubular Film Process for Producing Biaxially Oriented PA 6 Film”, Int. Polym. Proc., 19, 47–55 (2004a).
29 Takashige, M., et al., “Easy Tear Film of Biaxially Oriented PA6/MXD 6 Blend by Double Bubble Tubular Film Process”, Int. Polym. Proc., 19, 147–154 (2004b).
30 Takashige, M., Kanai, T., “Easy Tear Multilayer Film of Biaxially Oriented PA6/MXD6 by Double Bubble Tubular Film Process”, Int. Polym. Proc., 20, 100–104 (2005).
31 Takashide, M., Kanai T., “Physical Properties of Biaxially oriented PA6 Film for Simultaneous Stretching and Sequential Processing”, J. Polym. Eng., 31, 29–35 (2011)., DOI: 10.1515/polyeng.2011.005
32 Uehara, H., et al., “Deformation, Behavior, Processability and Physical Properties for Biaxially Oriented Film of LLDPE”, Int. Polym. Proc., 19, 155–162 (2004a).
33 Uehara, H., et al., “Stretchability and Properties of LLDPE Blends for Biaxially Oriented Film”, Int. Polym. Proc., 19, 163–171 (2004b).
34 Uehara, H., et al., “Stretchability and Properties of Various LLDPE for Biaxially Oriented Film”, Int. Polym. Proc., 19, 172–179 (2004c).
35 Wagner, M. H., Bernnat, A., “The Rheology of the Rheotens Test”, J. Rheol., 42, 917–928 (1998)., DOI: 10.1122/1.550907
36 White, J. L., Yamane, H., “A Collaborative Study of the Stability of Extrusion, Melt Spinning and Tubular Film Extrusion of some High-Low- and Linear-Low Density Polyethylene Samples”, Pure and Applied Chemistry, 59, 193–216 (1987)., DOI: 10.1351/pac198759020193
37 Zatloukal, M., Mavridis, H., Vlcek, J., Saha, P., “Modeling of Non-Isothermal Film Blowing Process by Using Variational Principles”, SPE ANTEC Tech. Papers, Charlotte, USA, p. 825–829 (2006).
38 Zatloukal, M., Vlcek, J., “Modeling of the Film Blowing Process by Using Variational Principles”, J. Non-Newtonian Fluid Mech., 123, 201–213 (2004)., DOI: 10.1016/j.jnnfm.2004.07.018
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